40 1 3 5 7-octatetraene molecular orbital diagram
If [1,3] or [1,7] hydrogen shifts were taking place, the deuterium atoms would be distributed equally among all eight carbon atoms. On prolonged heating, or at higher temperatures these cyclooctatrienes undergo electrocyclic ring opening to 1,3,5,7-octatetraene and reclosure to vinyl-1,3-cyclohexadienes.
1 3 5 7-octatetraene molecular orbital diagram
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